Author:

Keywords:

Science & Technology, Physical Sciences, Chemistry, Multidisciplinary, Chemistry, ZEOLITIC-IMIDAZOLATE FRAMEWORK, POROUS COORDINATION POLYMERS, NEGATIVE THERMAL-EXPANSION, LIQUID-PHASE EPITAXY, MOF THIN-FILM, TUNABLE ELECTRICAL-CONDUCTIVITY, ANHYDROUS PROTON CONDUCTION, ATOMIC LAYER DEPOSITION, SENSITIZED SOLAR-CELLS, INDUCED SPIN-CROSSOVER, 03 Chemical Sciences, General Chemistry, 34 Chemical sciences, 40 Engineering

Abstract:

Metal-organic frameworks (MOFs) are typically highlighted for their potential application in gas storage, separations and catalysis. In contrast, the unique prospects these porous and crystalline materials offer for application in electronic devices, although actively developed, are often underexposed. This review highlights the research aimed at the implementation of MOFs as an integral part of solid-state microelectronics. Manufacturing these devices will critically depend on the compatibility of MOFs with existing fabrication protocols and predominant standards. Therefore, it is important to focus in parallel on a fundamental understanding of the distinguishing properties of MOFs and eliminating fabrication-related obstacles for integration. The latter implies a shift from the microcrystalline powder synthesis in chemistry labs, towards film deposition and processing in a cleanroom environment. Both the fundamental and applied aspects of this two-pronged approach are discussed. Critical directions for future research are proposed in an updated high-level roadmap to stimulate the next steps towards MOF-based microelectronics within the community.