Network topology and cavity confinement-controlled diastereoselectivity in cyclopropanation reactions catalyzed by porphyrin-based MOFs

Epp, Konstantin; Bueken, Bart; Hofmann, Benjamin J; Cokoja, Mirza; Hemmer, Karina; De Vos, Dirk; Fischer, Roland A

doi:10.1039/c9cy00893d

Network topology and cavity confinement-controlled diastereoselectivity in cyclopropanation reactions catalyzed by porphyrin-based MOFs

Author:

Epp, Konstantin

Bueken, Bart ; Hofmann, Benjamin J ; Cokoja, Mirza ; Hemmer, Karina ; De Vos, Dirk ; Fischer, Roland A

Keywords:

Science & Technology, Physical Sciences, Chemistry, Physical, Chemistry, METAL-ORGANIC FRAMEWORKS, ASYMMETRIC CYCLOPROPANATION, HIGHLY EFFICIENT, CHIRAL LIGANDS, SELECTIVITY, INSERTION, ZEOLITE, BETA, 0302 Inorganic Chemistry, 0306 Physical Chemistry (incl. Structural), 0904 Chemical Engineering, 3402 Inorganic chemistry, 3405 Organic chemistry, 4004 Chemical engineering