Author:

Keywords:

sediment, co2 leakage, metal mobility, equilibrium leaching tests, geochemical modeling, mswi bottom ash, heavy-metals, ocean acidification, contaminated soils, leaching tests, estuarine sediments, northern spain, santander bay, waste, ph, Science & Technology, Life Sciences & Biomedicine, Environmental Sciences, Environmental Sciences & Ecology, Sediment, CO2 leakage, Metal mobility, Equilibrium leaching tests, Geochemical modeling, HEAVY-METALS, OCEAN ACIDIFICATION, CONTAMINATED SOILS, LEACHING BEHAVIOR, PH, MOBILITY, WASTE, TESTS, RISK, MSWI, Carbon Dioxide, Geologic Sediments, Metals, Seawater, Water Pollutants, Chemical

Abstract:

One of the main risks of CCS (Carbon Capture and Storage) is CO2 leakage from a storage site. The influence of CO2 leakage on trace metals leaching from contaminated marine sediment in a potential storage area (Northern Spain) is addressed using standardized leaching tests. The influence of the pH of the leaching solution on the leachates is evaluated using deionized water, natural seawater and acidified seawater at pH = 5, 6 and 7, obtained by CO2 bubbling. Equilibrium leaching tests (EN 12457) were performed at different liquid solid ratios and the results of ANC/BNC leaching test (CEN/TS 15364) were modeled using Visual Minteq. Equilibrium tests gave values of the final pH for all seawater leachates between 7 and 8 due to the high acid neutralization capacity of the sediment. Combining leaching test results and geochemical modeling provided insight in the mechanisms and prediction of trace metals leaching in acidified seawater environment. (C) 2011 Elsevier Ltd. All rights reserved.