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Title: An improved method for the measurement of strong flow birefringence
Authors: Zhang, Hua ×
Moldenaers, Paula
Mewis, Joannes #
Issue Date: Jul-1994
Publisher: Dr dietrich steinkopff verlag
Series Title: Rheologica acta vol:33 issue:4 pages:317-321
Abstract: An improved procedure is proposed to solve the problem of measuring strong birefringence on flowing samples which have a retardation delta larger than pi/2. The procedure can be applied to devices which are based on the modulation of the polarization vector with a high-speed rotating half-wave plate. It uses two optical configurations which have different responses to the retardation. By combining the information obtained from the two configurations, one can easily and accurately determine the actual retardation of the sample, irrespective of the quadrant in which the measured retardation is located, provided the sample is isotropic. This technique can also overcome the problem of large errors occurring in the vicinity of delta = (2m + 1)pi/2 due to the limited sensitivity around these values of delta. The use of the technique is illustrated with measurements on an isotropic solution of poly(benzyl glutamate) in m-cresol, which is strongly birefringent during shear flow.
ISSN: 0035-4511
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Chemical Engineering - miscellaneous
Soft Matter, Rheology and Technology Section
× corresponding author
# (joint) last author

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