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Title: Si-29 nuclear magnetic resonance of poly(methylphenyl)silane
Authors: DeMahieu, AF ×
Devaux, Jacques
Dereppe, C
Baudoux, G
Delhalle, J #
Issue Date: Apr-1996
Publisher: John wiley & sons inc
Series Title: Journal of polymer science part a-polymer chemistry vol:34 issue:5 pages:763-769
Abstract: A Cl-terminated poly(methylphenyl)silane is synthesized and analyzed by Si-29-NMR spectroscopy. Assignments are proposed for the different peaks observed. A modification of the chemical shifts of the peaks relative to the main chain atoms is observed upon heating. From these experimental results and computational calculations on model compounds, the assignments of the three main peaks to configurationally different Si atoms are confirmed. (C) 1996 John Wiley & Sons, Inc.
ISSN: 0887-624X
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Department of Materials Engineering - miscellaneous
× corresponding author
# (joint) last author

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