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Title: Validation of vapor phase decomposition - droplet collection - total reflection X-ray fluorescence spectrometry for metallic contamination analysis of silicon wafers
Authors: Hellin, David ×
Rip, Jens
Arnauts, Sophia
De Gendt, Stefan
Mertens, Paul
Vinckier, Christiaan #
Issue Date: Jan-2004
Publisher: Pergamon-elsevier science ltd
Series Title: Spectrochimica acta part b-atomic spectroscopy vol:59 issue:8 pages:1149-1157
Abstract: The combination of vapor phase decomposition -droplet collection (VPD-DC) with total reflection-X-ray fluorescence spectrometry (TXRF) is a well-established method for metallic contamination analysis of Si wafers. However, the efficiency of the methodology is not fully quantitatively understood. This study aims for the identification of the sources of error in the VPD-DC-TXRF process. From a study of systematic recovery rate (RR) on standard wafers, it is concluded that the VPD-DC method is very efficient in collecting impurities front Si wafers. TXRF saturation effect on the micro-droplet residue limits the accuracy of quantification to the levels below 3 X 10(13) atoms of metallic contamination. This represents a homogenous single element surface contamination of 1 x 10(11) at/cm(2) on a 200-mm wafer. Implications of this finding are more serious for multi-element contaminations and for larger wafer dimensions. The origin of this saturation effect is discussed and solutions are evaluated. Further, we suggest a monitoring of the scattered X-rays from VPD-DC residues as all indicator for TXRF accuracy. (C) 2004 Elsevier B.V. All rights reserved.
ISSN: 0584-8547
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Clinical Residents Medicine
Molecular Design and Synthesis
× corresponding author
# (joint) last author

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