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Title: On the stability of surface-confined nanoporous molecular networks
Authors: Ghijsens, Elke
Adisoejoso, Jinne
Van Gorp, Hans
Iris Destoop, Iris
Noguchi, Aya
Ivasenko, Oleksandr
Tahara, Kazukuni
Van der Auweraer, Mark
Tobe, Yoshito
De Feyter, Steven # ×
Issue Date: 5-Mar-2015
Publisher: American Institute of Physics
Series Title: Journal of Chemical Physics vol:142
Article number: 101932
Abstract: Self-assembly of molecular building blocks into two-dimensional nanoporous networks has been a topic of broad interest for many years. However, various factors govern the specific outcome of the self-assembly process, and understanding and controlling these are key to successful creation. In this work, the self-assembly of two alkylated dehydrobenzo[12]annulene building blocks was compared at the liquid-solid interface. It turned out that only a small chemical modification within the building blocks resulted in enhanced domain sizes and stability of the porous packing relative to the dense linear packing. Applying a thermodynamic model for phase transition revealed some key aspects for network formation.
ISSN: 0021-9606
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
× corresponding author
# (joint) last author

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