Title: Electrochemical film deposition of the zirconium metal-organic framework UiO-66 and application in miniaturized sorbent trap
Authors: Stassen, Ivo ×
Styles, Mark
Van Assche, Tom
Campagnol, Nicolo
Fransaer, Jan
Denayer, Joeri
Tan, Jin-Chong
Falcaro, Paolo
De Vos, Dirk
Ameloot, Rob #
Issue Date: 16-Feb-2015
Publisher: American Chemical Society
Series Title: Chemistry of Materials vol:27 issue:5 pages:1801-1807
Abstract: Film deposition is an enabling technology for integration of novel functional materials into real-world practical applications. We report both the anodic and cathodic electrochemical film deposition of UiO-66, a prototype of highly stable, zirconium-based metal−organic frameworks, using zirconium foil as the only metal source. The fundamentally different film formation mechanisms at the cathode and anode result in a significantly different coating adhesion strength, mainly due to the formation of an oxide film serving as a bridging layer at the anode. The patterned deposition capability of the electrochemical method enables the straightforward integration of UiO-66 as a sorbent film in a miniaturized sorbent trap for online analytical sampling and concentration of dilute volatile organic compounds.
ISSN: 0897-4756
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
Surface and Interface Engineered Materials
× corresponding author
# (joint) last author

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