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Keywords:

Polymers, Ionic liquids, Fuel cells, Membranes, Science & Technology, Physical Sciences, Chemistry, Inorganic & Nuclear, Chemistry, PROTON CONDUCTING MEMBRANES, COMPOSITE MEMBRANES, AROMATIC POLYMERS, THERMAL-STABILITY, HEAT-CAPACITIES, TEMPERATURE, PEEK, SOLVENTS, BLENDS, NAFION, 0302 Inorganic Chemistry, 0399 Other Chemical Sciences, Inorganic & Nuclear Chemistry, 3402 Inorganic chemistry

Abstract:

Ionic liquids (ILs), with their inherent ionic conductivity and negligible vapor pressure, can be exploited in proton exchange membrane (PEM) fuel cells for which thermal management is a major problem and the cell operation temperature is limited by the boiling point of water. In this work, sulfonated poly(ether ether ketone) (SPEEK) membranes were modified by the incorporation of tetrabutylphosphonium bromide ([P₄₄₄₄]Br) by solvent-casting. Electrochemical impedance spectroscopy (EIS) was used to study the electrical properties of the modified membranes. Simultaneous TGA and FTIR studies were used to evaluate the thermal stability and chemical structure of the modified membranes, respectively. 1H NMR spectroscopy was applied to probe the changes in the chemical environment due to the interaction between the ionic liquid and the polymer. Mechanical properties were studied by dynamic mechanical analysis. The temperature-dependent behavior of the viscosity of the [P₄₄₄₄]Br ionic liquid was observed to obey the Vogel–Fulcher–Tammann (VFT) equation, and was correlated to the ion-conducting properties of the IL-doped SPEEK membranes.