Title: Aniline and m-dinitrobenzene in NaY - Charge transfer complexes absorbed in a zeolitic host
Authors: Kirschhock, Christine ×
Fuess, H #
Issue Date: 1997
Publisher: Elsevier science bv
Series Title: Microporous materials vol:8 issue:1-2 pages:19-28
Abstract: The sites of aniline and m-dinitrobenzene simultaneously absorbed by NaY were studied by neutron powder diffraction. Selective deuteration of the molecules allows concise identification of the guests. These are stacked alternating along a threefold axis of spacegroup <Fd(3)over bar m>. UV diffuse reflectance spectrometry gives evidence of a charge transfer interaction between aniline and dinitrobenzene. The investigation of a sample containing two molecules of aniline per supercage yielded identical adsorption positions to those obtained in combination with dinitrobenzene.
ISSN: 0927-6513
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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