Hierarchically structured fibre reinforced poly mer (FRP) composites are a new generation of struc tural materials with high potential for tailored d esign. The increased degree of freedom in material selection and design is the main advantage o f these materials over conventional composites. Ho wever, the available literature still lacks a comp rehensive study on the structure-property relation ship and the interactions between the constit uents in these composite materials. This wor k aims at exploring various aspects of new hi erarchically structured carbon fibre polymer compo sites (CFRP) with the goal of understanding the in terplay between the different components in r elation to their mechanical properties and fractur e. Multiwall carbon nanotubes (CNTs) and a ph ase separating thermoplastic modifier (polyoxymeth ylene (POM)) are the main structural elements ¨used to form the microstructure of the studied ma terials. The principal approach adopted in t his work is to establish an initial understanding¨ of the structure-property relationship in binary ( POM/epoxy or CNT/epoxy) and ternary (POM/CNT/epoxy ) bulk resin blends. This involves a study of the¨ phase morphology, dynamic mechanical properties, a nd fracture toughness of various types of bulk res in blends with different compositions. At the next ¨step, fiber reinforced composites based on the pr eviously studied matrix blends are produced a nd characterized. Considering the challenges invol ved in the processing of the POM modified matrix b lends into the corresponding composites at high te mperature, a new manufacturing technique based on¨ resin transfer molding is developed and furth er optimized. The knowledge acquired during the st udy of the matrix blends is employed to expla in morphological observations as well as fracture¨ properties and damage behaviour monitored during q uasi-static tensile loading of the produced lamina tes. A correlation between the microstructure and phase morphology of the matrix and the proper ties of the laminates is established. It is shown that phase separated POM particles are able to enhance fracture toughness of bulk e poxy resins, as long as the particulate morph ology is dominant. Fracture toughness and ultimate ¨mechanical properties of the bulk resin materials ¨are shown to be highly sensitive to the phas e morphology of the phase-separated blend. Th erefore, any external factors affecting phase sepa ration of the thermoplastic modified blends can dr astically influence resulting properties. For ¨instance, it is illustrated that the presence of¨ fiber reinforcement changes the phase morphology o f the matrix and, hence, affects the transfer ¨of the toughness improvements of the bulk re sin to the laminates. Inclusion of CNTs is a lso shown to influence the phase morphology of the¨bulk resin as well as the microstructure of the r esulting hierarchical laminates. It is shown¨ that CNTs limit mass diffusion during phase separa tion of the thermoplastic phase, causing redu ction in the particle size of the resulting thermo plastic particles. This in turn affects the fractu re toughness of the bulk resin blends and damage d evelopment in the resulting CFRP laminate. In this part of the work, a new approach for incorpo ration of CNTs in the POM modified matrices is int roduced, in which the phase separating thermoplast ic particles are surrounded by clusters of CNT agg lomerates.