Title: Catalytically active gauze-supported skeletal nickel prepared from Ni–Zn alloys electrodeposited from an acetamide–dimethyl sulfone eutectic mixture
Authors: Fow, Kam Loon *
Murugan, Ganapathi *
Stassen, Ivo
Binnemans, Koen
Fransaer, Jan
De Vos, Dirk # ×
Issue Date: 2015
Publisher: Elsevier Science Publishers
Series Title: Catalysis Today vol:246 pages:191-197
Abstract: Nickel–zinc alloys were electrodeposited on copper gauze from an acetamide–dimethyl sulfone eutectic mixture containing nickel chloride and zinc chloride. The as-deposited nickel–zinc alloys have compact microstructures with very small crystallites (approximately 3 nm) and smooth surfaces. The nickel con-tent could be varied between 20 and 90 wt.% by controlling the temperature of the electrolyte. After alkaline leaching, a gauze-supported zinc based Raney nickel catalyst was obtained. The catalyst was benchmarked against commercial aluminum based Raney nickel in liquid phase hydrogenation of acetophenone. The gauze-supported zinc based skeletal nickel was more active and selective as compared to the commercial aluminum based Raney nickel. In addition, the gauze-supported zinc based Raney nickel catalyst could be reused without any hydrogen pretreatment. The activity of the reused catalyst decreased by 20%, but it retained its excellent selectivity.
ISSN: 0920-5861
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
Molecular Design and Synthesis
Surface and Interface Engineered Materials
* (joint) first author
× corresponding author
# (joint) last author

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