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Title: Synthesis, characterization, and catalytic properties of stable mesoporous alumino silicates assembled from preformed zeolite L precursors
Authors: Di, Yan ×
Yu, Y
Sun, YY
Yang, XY
Lin, S
Zhang, MY
Li, SG
Xiao, FS #
Issue Date: 2003
Publisher: Elsevier science bv
Series Title: Microporous and mesoporous materials vol:62 issue:3 pages:221-228
Abstract: Ordered mesoporous aluminosilicates designated as MAS-3 and MAS-8 with hexagonal mesopores have been hydrothermally synthesized from preformed zeolite L precursors under alkaline and strongly acidic conditions, respectively. MAS-3 and MAS-8 show good thermal and hydrothermal stability. Catalytic results in cracking cumene show that these mesoporous aluminosilicates are more active than conventional mesoporous aluminosilicates (Al-MCM-41). Characterization of infrared, N-2 adsorption isotherms, and temperature-programmed-desorption of ammonia (NH3-TPD) have also been used to investigate these materials and the results indicate that the walls of MAS-3 and MAS-8 contain the primary and secondary structural building units, which might be responsible for the high hydrothermal stability and good activities in catalysis. (C) 2003 Elsevier Inc. All rights reserved.
ISSN: 1387-1811
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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