Title: Peroxide reactions with anion-exchanged layered double hydroxide catalysts
Authors: De Vos, Dirk ×
Wahlen, Joos
Sels, Bert
Jacobs, Pierre #
Issue Date: 2002
Publisher: Georg thieme verlag kg
Series Title: Synlett issue:3 pages:367-380
Abstract: Layered double hydroxides (LDHs) are inorganic anion exchangers with basic surface properties. Combination of these LDHs with d(0) oxy-anions leads to a class of oxidatively stable and leak-free heterogeneous oxidation catalysts. Using peroxides as the oxidant, WO42--LDH and V10O286--LDH catalyze epoxidations; WO42--LDH effects bromide oxidation and bromide-assisted epoxidation; MoO42--LDH is an inorganic generator of O-1(2) from H2O2. The properties of these LDH catalysts can be finely adjusted in order to perform synthetically useful reactions.
ISSN: 0936-5214
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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