Title: ROMP and RCM catalysed by (R3P)(2)Cl2Ru=CHPh immobilised on a mesoporous support
Authors: Melis, K ×
De Vos, Dirk
Jacobs, Pierre
Verpoort, F #
Issue Date: 2001
Publisher: Elsevier science bv
Series Title: Journal of molecular catalysis a-chemical vol:169 issue:1-2 pages:47-56
Abstract: Heterogeneous hybrid catalysts with respect to the metathesis of olefins have been prepared by ligand exchange reaction between Ru-alkylidene complexes (Grubbs' type) and a phosphinated mesoporous matrix (P-MCM-41). The host/guest interaction is studied by FT-Raman, thermogravimetric analysis and N-2 adsorption. Catalytic tests in olefin metathesis reveal ROMP activity towards norbornene, even in aquatic environment, and a very high activity for the RCM of diallylamine and diethyldiallylmalonate. (C) 2001 Elsevier Science B.V. All rights reserved.
ISSN: 1381-1169
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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