Title: Electrodeposition of thick palladium coatings from a palladium(II)-containing ionic liquid
Authors: Schaltin, Stijn
Brooks, Neil R.
Sniekers, Jeroen
Van Meervelt, Luc
Binnemans, Koen
Fransaer, Jan # ×
Issue Date: 2014
Publisher: Royal Society of Chemistry
Series Title: Chemical Communications vol:50 issue:71 pages:10248-10250
Abstract: The first palladium-containing Liquid Metal Salts (LMS) are presented and shown to be suitable electrolytes for the electrodeposition of palladium. The homoleptic LMS of formula [Pd(MeIm)4][Tf2N]2 or [Pd(EtIm)4][Tf2N]2 (MeIm = N-methylimidazole, EtIm = N-ethylimidazole) have higher melting points than the heteroleptic [Pd(MeIm)2(EtIm)2][Tf2N]2, which is proved to be the most promising electrolyte. The deposition reaction in these LMS was found to be irreversible but smooth and dense palladium layers can be deposited that are crack-free up to a thickness of 10 microns.
ISSN: 1359-7345
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
Surface and Interface Engineered Materials
Biochemistry, Molecular and Structural Biology Section
× corresponding author
# (joint) last author

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