Title: Physico-Chemical Characterization of Nanofiltration Membranes
Authors: Boussu, Katleen ×
De Baerdemaeker, Jérémie
Dauwe, Charles
Weber, Marc
Lynn, Kelvin G
Depla, Diederik
Aldea, Steliana
Vankelecom, Ivo
Vandecasteele, Carlo
Van der Bruggen, Bart #
Issue Date: Feb-2007
Publisher: Wiley-VCH
Series Title: Chemphyschem vol:8 issue:3 pages:370-379
Abstract: This study presents a methodology for an in-depth characterization of six representative commercial nanofiltration membranes. Laboratory-made polyethersulfone membranes are included for reference. Besides the physical characterization [molecular weight cut-off (MWCO), surface charge, roughness and hydrophobicity], the membranes are also studied for their chemical composition [attenuated total reflectance Fourier spectroscopy (ATR-FTIR) and X-ray photoelectron spectroscopy (XPS)] and porosity [positron annihilation spectroscopy (PAS)]. The chemical characterization indicates that all membranes are composed of at least two different layers. The presence of an additional third layer is proved and studied for membranes with a polyamide top layer. PAS experiments, in combination with FIB (focused ion beam) images, show that these membranes also have a thinner and a less porous skin layer (upper part of the top layer). In the skin layer, two different pore sizes are observed for all commercial membranes: a pore size of 1.25-1.55 A as well as a pore size of 3.20-3.95 A (both depending on the membrane type). Thus, the pore size distribution in nanofiltration membranes is bimodal, in contrast to the generally accepted log-normal distribution. Although the pore sizes are rather similar for all commercial membranes, their pore volume fraction and hence their porosity differ significantly.
ISSN: 1439-4235
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Process Engineering for Sustainable Systems Section
Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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