Acta crystallographica. Section C, Crystal structure communications
Publication date:
2004-07-03
Volume:
56
Pages:
E98 -
E99
Author:
Novoa De Armas, Hector
Pérez, H ; Peeters, Oswald ; Blaton, Norbert ; De Ranter, Camiel ; López, JM
Keywords:
3402 Inorganic chemistry, 3403 Macromolecular and materials chemistry
Abstract:
The title compound, (C(6)H(5)CH(2))(3)PO, is an organic tertiary phosphine oxide. The molecule has threefold symmetry, with the P-O bond along the threefold axis. Main dimensions include P-O 1.488 (4), P-C 1.823 (3) A and O-P-C 114.7 (1) degrees. The crystals were accidentally obtained when preparing complexes of nickel(II) with dibenzylphosphine.