ITEM METADATA RECORD
Title: Scope and limitations of a new highly selective synthesis of unsymmetrical monomers for the synthesis of precursors toward poly(arylenevinylene)s
Authors: Van Der Borght, Mik ×
Vanderzande, Dirk
Adriaensens, Peter
Gelan, Jan #
Issue Date: 2000
Publisher: American Chemical Society
Series Title: Journal of Organic Chemistry vol:65 issue:2 pages:284-289
Abstract: In our laboratory a precursor route to poly(p-phenylenevinylene) derivatives is developed in which
unsymmetrically substituted p-xylene derivatives, possessing a benzylic sulfinylalkyl group, are used as monomers. Because of this unsymmetry, we were forced to investigate thoroughly the synthesis of these sulfoxides, as we start from symmetric and readily accessible molecules, namely, bis(halomethyl)-p-xylene derivatives. In a former publication, a new extremely effective route for
the production of these unsymmetrically substituted sulfinyl monomers was presented. This paper expands upon these previously reported results. To examine the scope and limitations of this elegant route, this new method was applied to the synthesis of various derivatives not included in the initial work.
ISSN: 0022-3263
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Bioengineering Technology TC, Technology Campus Geel
Technologiecluster Bioengineering Technologie
× corresponding author
# (joint) last author

Files in This Item:
File Description Status SizeFormat
Van Der Borght (2000) Scope and limitations of a new highly selective synthesis of unsymmetrical monomers for the synthesis of precursors toward poly(arylenevinylene)s.pdf Published 135KbAdobe PDFView/Open Request a copy

These files are only available to some KU Leuven Association staff members

 




All items in Lirias are protected by copyright, with all rights reserved.

© Web of science