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Title: Adiabatic scanning calorimetry study of ionic liquid crystals with highly ordered crystal smectic phases
Authors: Tripathi, Chandra Shekhar
Leys, Jan
Losada-Pérez, Patricia
Lava, Kathleen
Binnemans, Koen
Glorieux, Christ
Thoen, Jan
Issue Date: 2013
Publisher: Taylor & Francis
Series Title: Liquid Crystals vol:40 issue:3 pages:433-433
Abstract: Adiabatic scanning calorimetry was used to study four ionic liquid crystals whose phase sequences include highly
ordered crystal smectic phases (crystal smectic E or T phases). The ionic liquids were based on piperidinium
or morpholinium cations with long alkyl chains; the anions were tetrafluoroborate or hexafluorophosphate.
High-resolution heat capacity and enthalpy data were obtained, from which the total transition heat and latent
heat for the observed phase transitions were determined. All transitions displayed a non-zero latent heat and were
thus found to be first order.
ISSN: 0267-8292
Publication status: published
KU Leuven publication type: DI
Appears in Collections:Molecular Design and Synthesis
Soft Matter and Biophysics

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