Title: Interplay of Metal Node and Amine Functionality in NH2-MIL-53: Modulating Breathing Behavior through Intra-framework Interactions
Authors: Serra-Crespo, Pablo ×
Gobechiya, Elena
Ramos-Fernandez, Enrique
Juan-Alcaniz, Jana
Martinez-Joaristi, Alberto
Stavitski, Eli
Kirschhock, Christine
Martens, Johan
Kapteijn, Freek
Gascon, Jorge #
Issue Date: 2012
Publisher: American Chemical Society
Series Title: Langmuir vol:28 issue:35 pages:12916-12922
Abstract: A series of amino-functionalized MIL-53 with different metals as nodes has been synthesized. By determining adsorption properties and spectroscopic characterization, we unequivocally show that the interaction between
the amines of the organic linker and bridging μ2-OH of the inorganic scaffold modulates metal organic framework (MOF) flexibility. The strength of the interaction has been found to correlate with the electropositivity of the metal.
ISSN: 0743-7463
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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