ITEM METADATA RECORD
Title: Hyper-rayleigh scattering in solution
Authors: Clays, Koen ×
Persoons, Andre #
Issue Date: Jan-1991
Publisher: American physical soc
Series Title: Physical review letters vol:66 issue:23 pages:2980-2983
Abstract: Hyper-Rayleigh scattering in solution is used for the determination of the hyperpolarizability of non-linear optical molecules. Obtaining the first hyperpolarizability-beta without having to independently determine the dipole moment-mu and the second hyperpolarizability-gamma is an advantage over the electric-field-induced second-harmonic generation technique. Values of the first hyperpolarizability-beta of 23 x 10(-30) esu for para-nitroaniline, 105 X 10(-30) esu for 4-methoxy-4'-nitrostilbene, and 95 x 10(-30) esu for 4-hydroxy-4'-nitrostilbene dissolved in chloroform have been obtained. The equivalent-internal-field model is shown to hold for small saturated molecules.
URI: 
ISSN: 0031-9007
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
× corresponding author
# (joint) last author

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