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Title: Lanthanide containing Schiff's base complexes with chloride counter-ions: mesomorphic properties
Authors: Van Deun, Rik ×
Binnemans, Koen #
Issue Date: 2001
Publisher: Elsevier science bv
Series Title: Materials science & engineering c-biomimetic and supramolecular systems vol:18 issue:1-2 pages:211-215
Abstract: Liquid crystalline lanthanide complexes (metallomesogens) with chloride counter-ions have been synthesized. The complexes have the stoichiometry [Ln(LH)3Cl3], where Ln is a trivalent rare-earth ion (Y, Pr, Sm, Eu-Lu), and LH is the ligand N-octadecyl-4-octyloxysalicylaldimine. Although the Schiff's base ligands do not exhibit mesomorphism, the complexes do (SmA phase). The mesomorphic behaviour of these compounds has been investigated by hot-stage polarized microscopy, differential scanning calorimetry (DSC) and high temperature X-ray diffraction measurements. The stoichiometry of the complexes remains constant throughout the lanthanide series. The complexes have rather high transition temperatures.
URI: 
ISSN: 0928-4931
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
× corresponding author
# (joint) last author

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