Title: Structure of [UO2Cl4](2-) in acetonitrile
Authors: Servaes, Kelly ×
Hennig, C
Van Deun, Rik
Görller-Walrand, Christiane #
Issue Date: Jan-2005
Publisher: Amer chemical soc
Series Title: Inorganic Chemistry vol:44 issue:22 pages:7705-7707
Abstract: The complex formation of uranyl UO22+ with chloride ions in acetonitrile was studied by UV-vis and U L-III EXAFS spectroscopy. The investigations unambiguously point to the existence of a [UO2Cl4](2-) species in solution with D-4h symmetry. The distances in the U(VI) coordination sphere are U-O-ax = 1.77 +/- 0.01 angstrom and U-Cl = 2.68 +/- 0.01 angstrom.
ISSN: 0020-1669
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
Chemistry - miscellaneous
× corresponding author
# (joint) last author

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