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Title: Morphology of homogeneous copolymers of ethylene and 1-octene. III. Structural changes during heating as revealed by time-resolved SAXS and WAXD
Authors: Goderis, Bart
Peeters, M
Mathot, Vincent
Koch, MHJ
Bras, W
Ryan, AJ
Reynaers, Harry #
Issue Date: Jan-2000
Publisher: John wiley & sons inc
Series Title: Journal of polymer science part b-polymer physics vol:38 issue:15 pages:1975-1991
Abstract: The structural changes of two linear polyethylenes, LPEs, with different molar mass and of two homogeneous copolymers of ethylene and 1-octene with comparable comonomer content but different molar mass were monitored during heating at 10 degrees C per minute using synchrotron radiation SAXS. Two sets of samples, cooled at 0.1 degrees C per minute and quenched in liquid nitrogen, respectively, were studied. All LPEs display surface melting between room temperature and the end melting temperature, whereas complete melting, according to lamellar thickness, only occurs at the highest temperatures where DSC displays a pronounced melting peak. There is recrystallization followed by isothermal lamellar thickening if annealing steps are inserted. The lamellar crystals of slowly cooled homogeneous copolymers melt in the reverse order of their formation, that is, crystals melt according to their thickness. Quenching creates unstable crystals through the cocrystallization of ethylene sequences with different length. These crystals repeatedly melt and co-recrystallize during heating. The exothermic heat due to recrystallization partially compensates the endothermic heat due to melting resulting in a narrow overall DSC melting peak with its maximum at a higher temperature than the melting peak of slowly cooled copolymers. With increasing temperature, the crystallinity of quenched copolymers overtakes the one of slowly cooled samples due to co-recrystallization by which an overcrowding of leaving chains at the crystal surfaces is avoided. (C) 2000 John Wiley & Sons, Inc.
ISSN: 0887-6266
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
Chemistry - miscellaneous
Translational Research in GastroIntestinal Disorders
Polymer Chemistry and Materials
# (joint) last author

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