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Title: Magnetic anisotropy in the excited states of low symmetry lanthanide complexes
Authors: Ungur, Liviu ×
Chibotaru, Liviu #
Issue Date: 25-Oct-2011
Publisher: Royal Society of Chemistry
Series Title: Physical Chemistry Chemical Physics vol:13 issue:45 pages:20086-20090
Abstract: Ab initio investigation of multiplet spectrum of lanthanides in archetypal coordination geometries shows an unexpected regular structure consisting of (i) mirror symmetry of anisotropic magnetic properties of doublet states, (ii) high magnetic axiality of low-lying and high-lying doublets, comparable to complexes with ideal axial symmetry, and (iii) the strong rotation of the anisotropy axes of individual doublets. The obtained high axiality of the ground doublet states explains the SMM behaviour of low-symmetry lanthanide complexes.
URI: 
ISSN: 1463-9076
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Non-KU Leuven Association publications
× corresponding author
# (joint) last author

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