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Title: Rate-constant of the alpha-pinene plus atomic-hydrogen reaction at 295-k
Authors: Vinckier, Christiaan ×
Vanhoof, N #
Issue Date: Jan-1994
Publisher: John wiley & sons inc
Series Title: International journal of chemical kinetics vol:26 issue:5 pages:527-534
Abstract: The rate constant of the reaction of alpha-pinene with atomic hydrogen was determined at 295 K using the fast-flow reactor technique directly coupled to a mass spectrometric detection technique. The value was found to be equal to (9.8 +/- 3.3) x 10(-13) cm3 molecules-1 s-1 and independent of the helium pressure between 1 and 2 torr. The major reaction product formed is pinane showing that the stabilization of the adduct radical C10H17*, followed by a subsequent hydrogen atom addition step, is the important reaction route. (C) 1994 John Wiley & Sons, Inc.
ISSN: 0538-8066
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
× corresponding author
# (joint) last author

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