Title: Identifiability of competitive intermolecular three-state excited-state processes
Authors: Boens, Noël ×
Kowalczyk, A #
Issue Date: Jan-1996
Publisher: Elsevier science bv
Series Title: Chemical Physics Letters vol:260 issue:3-4 pages:326-330
Abstract: The conditions necessary for the recovery of the rate constants from fluorescence decay traces due to competitive intermolecular three-state excited-state processes are investigated. The studied system models a situation where an excited-state species can react competitively with both co-reactants X and Y. It is demonstrated theoretically that, if fluorescence decay traces at two concentrations of X and two concentrations of Y are available, all seven rate constants can always be recovered. In contrast to previously studied intermolecular two-state and three-state excited-state processes, it is not required to obtain a fluorescence decay at [X] = [Y] = 0 M to assign unique numerical values to all rate constants.
ISSN: 0009-2614
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
× corresponding author
# (joint) last author

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