Title: Synthesis of novel dendritic molecules based on pyrroloanthracene units
Authors: Smet, Mario ×
Corens, D
Dehaen, Wim #
Issue Date: Jan-2003
Publisher: Arkat usa inc
Series Title: Arkivoc pages:51-67
Abstract: Novel pyrroloanthracenes were efficiently synthesized starting from Diels-Alder adducts of anthracene. Some of these orthogonally bridged, rigid and bulky compounds were used as building blocks for the construction of monodisperse dendritic macromolecules. Molecular masses over 4 kDa could be obtained. Further propagation was problematic because of the particular stability of the 4-(1-pyrrolyl) benzyl cation causing the instability or difficulty of formation of the analogous benzyl ether linkage in the proposed dendritic structures.
ISSN: 1551-7004
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
Polymer Chemistry and Materials
× corresponding author
# (joint) last author

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