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Title: Structural Identification of Caged Vanadium Doped Silicon Clusters
Authors: Claes, Pieterjan
Janssens, Ewald ×
Vu Thi, Ngan
Gruene, Philipp
Lyon, John T.
Harding, Dan J.
Fielicke, André
Nguyen, Minh
Lievens, Peter #
Issue Date: Oct-2011
Publisher: American Physical Society
Series Title: Physical Review Letters vol:107 issue:17 pages:-
Article number: 173401
Abstract: The geometry of cationic silicon clusters doped with vanadium, SinV+ (n = 12-16), is investigated by using infrared multiple photon dissociation of the corresponding rare gas complexes in combination with ab initio calculations. It is shown that the clusters are endohedral cages, and evidence is provided that Si16V+ is a fluxional system with a symmetric Frank-Kasper geometry.
ISSN: 0031-9007
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Solid State Physics and Magnetism Section
Quantum Chemistry and Physical Chemistry Section
× corresponding author
# (joint) last author

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