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Title: Kinetics of the formation, and optical absorption study of [IrCl5(CH3CN)](2-) in solution
Authors: D'Olieslager, J ×
Görller-Walrand, Christiane
Schoutens, Kristel
Gilliams, B #
Issue Date: Jan-1998
Publisher: Pergamon-elsevier science ltd
Series Title: Polyhedron vol:17 issue:10 pages:1773-1778
Abstract: In this paper the kinetics of the reaction of [IrCl5(H2O)](2-) with CH3CN has been studied. The reaction product was isolated and identified as K-2[IrCl5(CH3CN)]. 2H(2)O. The experimental rate constants show no constant order with respect to the acetonitrile concentration. A preferential solvation of [IrCl5(H2O)](2-) by acetonitrile in water-acetonitrile mixtures is suggested to explain the data. The obtained optical absorption spectra of [IrCl5(CH3CN)](2-) are in good agreement with data already published, but another interpretation is given for the observed d-d transitions. The low energy transition at about 24,000 cm(-1) is predicted to be a singlet-singlet transition ((1)A(2) <-- (1)A(1)), and not a singlet-triplet transition as proposed in other work. (C) 1998 Elsevier Science Ltd. All rights reserved.
URI: 
ISSN: 0277-5387
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
× corresponding author
# (joint) last author

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