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Title: Tuning octopolar NLO chromophores: Synthesis and spectroscopic characterization of persubstituted 1,3,5-tris(ethynylphenyl)benzenes
Authors: Hennrich, G ×
Asselberghs, Inge
Clays, Koen
Persoons, Andre #
Issue Date: Jan-2004
Publisher: Amer chemical soc
Series Title: Journal of Organic Chemistry vol:69 issue:15 pages:5077-5081
Abstract: The synthesis of a series of octopolar 1,3,5-tris(ethynylphenyl)benzenes via Sonogashira coupling is described, varying the substituents on both the central benzene core as well as the acetylenic periphery. In particular, systems bearing an electron-rich core and an electron-poor periphery are obtained that display advanced optical properties. The linear (by UV-vis and fluorescence spectroscopy) and second-order nonlinear optical properties are studied, the latter by hyper-Rayleigh scattering (HRS) (Hendrickx, E.; Clays, K.; Persoons, A. Acc. Chem. Res. 1998, 31, 675-683). The influence of different core and periphery substitution is revealed by the optical properties and confirms the possibility of fine-tuning those. Because of the presence of (one-photon) fluorescence for all compounds, femtosecond hyper-Rayleigh scattering has been applied (Olbrechts, G.; Strobbe, R.; Clays, K.; Persoons, A. Rev. Sci. Instrum. 1998, 69, 2233-2241). The implementation of the deconvolution in the frequency domain allows for a demodulation and a phase shift between immediate (nonlinear) scattering and time-delayed (multiphoton) fluorescence for high modulation frequencies (Wostyn, K.; Binnemans, K.; Clays, K.; Persoons, A. Rev. Sci. Instrum. 2001, 72, 32153220). In accordance with the linear optical properties, the second-order NLO properties can also be tuned by varying the core and peripheric substitutents.
URI: 
ISSN: 0022-3263
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
× corresponding author
# (joint) last author

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