Title: Matrix-isolation ft-ir study on the protomeric tautomerism 2-hydroxypyridine-reversible-2-pyridone
Authors: Smets, J ×
Maes, Guido #
Issue Date: Jan-1991
Publisher: Elsevier science bv
Series Title: Chemical Physics Letters vol:187 issue:5 pages:532-536
Abstract: The vibrational spectrum of 2-hydroxypyridine isolated in an Ar matrix was studied using FT-IR spectroscopy. From experimental intensities of different pairs of bands assigned to the 2-oxo-(P2) and the 2-hydroxy-(HP2) tautomer respectively, a tautomerization constant of 0.40 +/- 0.10 was calculated at 303 K, in excellent agreement with recent theoretical predictions. However, the P2 form is more abundant in a low temperature matrix than recently suggested by theoretical calculations,
ISSN: 0009-2614
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Quantum Chemistry and Physical Chemistry Section
Centre for Sociological Research
× corresponding author
# (joint) last author

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