Title: Benzimidazole-functionalized dendrons as molybdenum supports for selective epoxidation catalysis
Authors: Chavan, S ×
Maes, Wouter
Wahlen, Joos
Jacobs, Pierre
De Vos, Dirk
Dehaen, Wim #
Issue Date: Mar-2005
Publisher: Elsevier
Series Title: Catalysis Communications vol:6 issue:3 pages:241-246
Abstract: Novel, benzimidazole-functionalized dendrons of successive generations (G(0)-G(2)) were synthesized and characterized by NMR spectroscopic and MS spectrometric techniques. Immobilization of Mo on these dendrons leads to oxidatively stable, highly efficient and selective catalysts for epoxidation of cyclohexene with t-butyl hydroperoxide as oxidant. A unique feature of the dendritic Mo complex catalysts is their heterogeneous nature, which facilitates their recuperation. (C) 2005 Elsevier B.V. All rights reserved.
ISSN: 1566-7367
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
Molecular Design and Synthesis
× corresponding author
# (joint) last author

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