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Title: Correlation between ground state conformation and excited state dynamics in a multichromophoric dendrimer studied by excitation wavelength dependent fluorescence upconversion
Authors: Karni, Y ×
Jordens, Sven
De Belder, Gino
Hofkens, Johan
Schweitzer, Gerd
De Schryver, Frans
Herrmann, A
Mullen, K #
Issue Date: Jan-1999
Publisher: Amer chemical soc
Series Title: Journal of Physical Chemistry B vol:103 issue:43 pages:9378-9381
Abstract: A time-resolved fluorescence upconversion study on a polyphenylene dendrimer with 16 peryleneimide chromophores at the rim, in which the excitation wavelength is systematically varied while the detection wavelength is kept constant, is reported. A new setup is described which allows excitation at wavelengths as short as 320 nm and throughout the visible range up to 900 nm with a system prompt response on the order of 300 fs. In addition to results reported previously(13) which were obtained at shorter wavelengths indicating the initial formation of a locally excited state which then evolves further into a locally excited state on a 5 ps time scale, the newly obtained data at longer wavelength excitation show the existence of a ground state interaction leading under these conditions of excitation predominantly to a directly formed complex.
ISSN: 1089-5647
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
× corresponding author
# (joint) last author

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