Title: Reversible switching of the first hyperpolarisability of an NLO-active donor-acceptor molecule based on redox interconversion of the octamethylferrocene donor unit
Authors: Malaun, M ×
Reeves, ZR
Paul, RL
Jeffery, JC
McCleverty, JA
Ward, MD
Asselberghs, Inge
Clays, Koen
Persoons, AE #
Issue Date: Jan-2001
Publisher: Royal soc chemistry
Series Title: Chemical communications issue:01 pages:49-50
Abstract: Compound 1, containing an octamethylferrocene donor linked to a nitrothiophene acceptor via an ethenyl linker, shows a static first hyperpolarisability beta (0) of 95(+/- 10) x 10(-30) esu, which is reduced to 10(+/-2) x 10(-30) esu on oxidation of the octamethylferrocene unit; this provides for a simple redox-based switching of the NLO characteristics of the compound.
ISSN: 1359-7345
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
× corresponding author
# (joint) last author

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