Title: End Group-Functionalization and Synthesis of Block-Copolythiophenes by Modified Nickel Initiators
Authors: Smeets, Alfons ×
Willot, Pieter
De Winter, Julien
Gerbaux, Pascal
Verbiest, Thierry
Koeckelberghs, Guy #
Issue Date: 13-Jul-2011
Publisher: American Chemical Society
Series Title: Macromolecules vol:44 issue:15 pages:6017-6025
Abstract: Polythiophenes with alcohol, tosylate, azide, ethynylene, carboxylic acid, and amine end groups were prepared by a combination of functionalized nickel initiators and postpolymerization reactions. The azide and ethynylene polymers were subsequently used in a click reaction to produce a conjugated block copolymer. Finally, a conjugated triblock-copolymer was synthesized by means of a chain growth polymerization initiated by a binuclear nickel initiator.
ISSN: 0024-9297
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
Polymer Chemistry and Materials
× corresponding author
# (joint) last author

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