Title: Affinity of divalent mercury towards nitrogen donor ligands
Authors: Meyer, G ×
Nockemann, Peter #
Issue Date: Jan-2003
Publisher: Wiley-v c h verlag gmbh
Series Title: Zeitschrift fur anorganische und allgemeine chemie vol:629 issue:9 pages:1447-1461
Abstract: As with gold, relativistic effects are important in the chemistry of mercury Together with the closed-shell d(10) configuration of Hg2+ they account for the special bonding schemes as preferred linear coordination with highly covalent contributions to chemical bonding or special affinities to nitrogen and sulfur that are so prominent in mercuric chemistry This research report summarizes recent research on coordination compounds with halogen, oxygen and, especially, nitrogen as direct bonding partners of di-valent mercury and their competition with each other. In a rather systematic way N-donor ligands with one, two and more than two nitrogen atoms have been inspected in order to elucidate the influences that lead to the special bonding schemes of Hg-II-N compounds.
ISSN: 0044-2313
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
× corresponding author
# (joint) last author

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