Title: Symmetry related [(Dy6Mn12III)-Mn-III] cores with different magnetic anisotropies
Authors: Liu, Jun-Liang ×
Guo, Fu-Sheng
Meng, Zhao-Sha
Zheng, Yan-Zhen
Leng, Ji-Dong
Tong, Ming-Liang
Ungur, Liviu
Chibotaru, Liviu F.
Heroux, Katie J.
Hendrickson, David N. #
Issue Date: 2011
Publisher: Royal Society of Chemistry
Series Title: Chemical Science vol:2 issue:7 pages:1268-1272
Abstract: Two heterometallic [(Dy6Mn12III)-Mn-III] clusters comprising of the same [(Mn8O13)-O-III] fragment, four isolated Mn-III ions and two linear [Dy-3(III)] units have been synthesised. Except for the same composition, the main difference of these two cores lies in the coordination environment and the orientations of the linear [Dy-3(III)] units. This difference leads to an alternation in the symmetry of the two cores that significantly modulates their magnetic properties including ground spin state and slow relaxation behavior.
ISSN: 2041-6520
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Quantum Chemistry and Physical Chemistry Section
× corresponding author
# (joint) last author

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