Title: A Rare mu(4)-O Centred Dy-4 Tetrahedron with Coordination-Induced Local Chirality and Single-Molecule Magnet Behaviour
Authors: Lin, Po-Heng ×
Korobkov, Ilia
Wernsdorfer, Wolfgang
Ungur, Liviu
Chibotaru, Liviu F.
Murugesu, Muralee #
Issue Date: Apr-2011
Publisher: Wiley-VCH
Series Title: European Journal of Inorganic Chemistry issue:10 pages:1535-1539
Abstract: Coordination-induced chirality was achieved in a unique tetrahedral [Dy-4(mu(4)-O)(mu-OMe)(2)(beh)(2)(esh)(4)]center dot 3MeOH complex through a twisted diazine bridge from a Schiff base ligand. Magnetic measurements reveal weak intramolecular antiferromagnetic interactions (J = -0.3 cm(-1)) with single-molecule magnet behaviour (U-eff = 23.42 K).
ISSN: 1434-1948
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Quantum Chemistry and Physical Chemistry Section
× corresponding author
# (joint) last author

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