Title: A Non-sandwiched Macrocyclic Monolanthanide Single-Molecule Magnet: The Key Role of Axiality
Authors: Feltham, Humphrey L. C. ×
Lan, Yanhua
Kloewer, Frederik
Ungur, Liviu
Chibotaru, Liviu F.
Powell, Annie K.
Brooker, Sally #
Issue Date: Apr-2011
Publisher: VCH Verlagsgesellschaft
Series Title: Chemistry - a European Journal vol:17 issue:16 pages:4362-4365
Abstract: The dynamic behavior of the tetranuclear zinc(II)–dysprosium(III) complex of the hexaimine [3+3] macrocycle (LPr)6− under an external DC field (1500 Oe) indicates that it is a single-molecule magnet (SMM). It is the first to contain a single lanthanide ion (in orange, see graphic) coordinated inside the cavity of a single macrocyclic ligand and thus represents a new class of SMM.
ISSN: 0947-6539
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Non-KU Leuven Association publications
× corresponding author
# (joint) last author

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