Title: A Spectroscopic Investigation of Magnetic Exchange Between Highly Anisotropic Spin Centers
Authors: Boeer, Angelika B
Barra, Anne-Laure
Chibotaru, Liviu F.
Collison, David
McInnes, Eric J. L. ×
Mole, Richard A.
Simeoni, Giovanna G.
Timco, Grigore A.
Ungur, Liviu
Unruh, Tobias
Winpenny, Richard E. P. #
Issue Date: 2011
Publisher: Wiley-VCH
Series Title: Angewandte Chemie - International Edition vol:50 issue:17 pages:4007-4011
Abstract: The exchange and Zeeman parameters of two dimetallic, six-coordinate cobalt(II) compounds—i.e., with orbitally degenerate metal ions—have been determined by a combination of high-resolution EPR and INS spectroscopies, together with ab intio calculations. It is suggested that the correlation between the local crystal field about the CoII centers and the superexchange pathway controls the magnetic interaction.
ISSN: 1433-7851
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Quantum Chemistry and Physical Chemistry Section
× corresponding author
# (joint) last author

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