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Title: Direct growth of Keggin polyoxometalates incorporated copper 1,3,5-benzenetricarboxylate metal organic framework films on a copper metal substrate
Authors: Kayaert, Sam ×
Bajpe, Sneha
Masschaele, Kasper
Breynaert, Eric
Kirschhock, Christine
Martens, Johan #
Issue Date: Jun-2011
Publisher: Elsevier Sequoia
Series Title: Thin Solid Films vol:519 issue:16 pages:5437-5440
Abstract: Keggin heteropolyacid incorporated Cu-3(BTC)(2) (BTC=1,3,5-benzenetricarboxylic acid) thin films were grown on metallic Cu substrates in various solvents at ambient conditions. The Keggin heteropolyacid templated the growth of Cu-3(BTC)(2) crystals while the Cu substrate served as CO2+-ion source. To obtain smooth, homogeneous films the optimal growth conditions found were in an ethanolic solution in contact with ambient air. X-ray diffraction measurements showed a preferred (100) orientation of the Cu-3(BTC)(2) crystals in ethanol while the use of a water-based solvent yielded a dominating (111) orientation. (C) 2011 Elsevier B.V. All rights reserved.
URI: 
ISSN: 0040-6090
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Centre for Surface Chemistry and Catalysis
× corresponding author
# (joint) last author

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