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Title: The gelation mechanism of solutions of isotactic polystyrene in cis-decalin
Authors: De Rudder, Jan
Berghmans, Hugo
Roels, T
Jacobs, A #
Issue Date: Jan-2001
Publisher: Elsevier science bv
Series Title: Colloids and Surfaces A, Physicochemical and Engineering Aspects vol:183 pages:313-326
Abstract: The gelation of isotactic polystyrene in cis-decalin was investigated with calorimetric, infrared and theological measurements. At temperatures above 30 degreesC a crystalline structure similar to the one obtained by crystallization from the melt is formed. Below 30 degreesC thermoreversible gels are formed with a molecular conformation different from that in the melt crystallized samples. They can be formed during a cooling process below 19 degreesC and can increase their helix content and modulus on isothermal annealing. Gels formed in this temperature domain exhibit a two-stage melting as observed by calorimetry, infrared spectroscopy and rheology. At higher temperature gels can only be formed after isothermal annealing. These gels melt in one single step. A mechanism is proposed for the gelation in both temperature domains. At low temperature, bundle-like entities composed of long helices are formed giving rise to the high melting structure. In a second step, additional helix formation increases the modulus and induces the low melting structure. In the high temperature domain, only the low melting structure is formed. This model is in agreement with morphological data reported in the literature. (C) 2001 Elsevier Science B.V. All rights reserved.
URI: 
ISSN: 0927-7757
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Chemistry - miscellaneous
Molecular Imaging and Photonics
# (joint) last author

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