A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics

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Title:	A comparison of the pentaammine(pyridyl)ruthenium(II) and 4-(dimethylamino)phenyl groups as electron donors for quadratic non-linear optics
Authors:	Coe, BJ × Harris, JA Clays, Koen Persoons, Andre Wostyn, Kurt Brunschwig, BS #
Issue Date:	Jan-2001
Publisher:	Royal soc chemistry
Series Title:	Chemical communications issue:17 pages:1548-1549
Abstract:	Hyper-Rayleigh scattering and Stark spectroscopic studies show that the complex salts [1-4]PF6 have larger static first hyperpolarizabilities beta (0) than [5-8]PF6, because the higher HOMO energy of a {Ru-II(NH3)(5)}(2+) centre more than offsets the superior pi -orbital overlap in the purely organic chromophores.
ISSN:	1359-7345
Publication status:	published
KU Leuven publication type:	IT
Appears in Collections:	Molecular Imaging and Photonics

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