Title: Synthesis of novel dendrimers containing pyrimidine units
Authors: Maes, Wouter ×
Amabilino, DB
Dehaen, Wim #
Issue Date: Jan-2003
Publisher: Pergamon-elsevier science ltd
Series Title: Tetrahedron vol:59 issue:22 pages:3937-3943
Abstract: A novel convergent approach to dendritic macromolecules is described in which 4,6-dichloro-2-(4-methoxyphenyl)-pyrimidine is used as the building block. The nucleophilic aromatic substitution reaction at this AB(2)-monomer was used as the key step in the propagation of the dendrons. Different core reagents were used to form the dendrimers, including a 5,15-bis(pyrimidyl)porphyrin core. Fourth-generation dendrons and third-generation dendrimers could be synthesized. The presented dendrimers are promising candidates to be used in applications where a more rigid structure and a larger resistance towards the applied conditions is required. (C) 2003 Elsevier Science Ltd. All rights reserved.
ISSN: 0040-4020
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
× corresponding author
# (joint) last author

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