Title: Lewis acid catalyzed hetero Diels-Alder reactions of olefinic and acetylenic compounds with 6-methyl-3,5-dichloro-2H-1,4-oxazin-2-one
Authors: De Borggraeve, Wim
Rombouts, Frederik
Van der Eycken, Erik
Hoornaert, GJ # ×
Issue Date: Jan-2000
Publisher: Georg thieme verlag
Series Title: Synlett issue:5 pages:713-715
Abstract: For the first time Lewis acid catalysis is described for the hetero Diels-Alder reaction of a conformationally fixed 2-azadiene system in a 2H-1,4-oxazin-2-one with a variety of alkenes and alkynes. The reaction is shown to occur under much milder conditions as hitherto reported. With dienophiles containing no heteroatoms an important increase in regio- and/or stereoselectivity is observed.
ISSN: 0936-5214
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
Afdeling Organische synthese
× corresponding author
# (joint) last author

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