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Title: Nitrogen-containing macrocycles as host molecules for the recognition of undissociated phenol derivatives: Mechanism of potentiometric signal generation
Authors: Radecki, J ×
Dehaen, Wim #
Issue Date: Jan-2006
Publisher: Bentham science publ ltd
Series Title: Combinatorial chemistry & high throughput screening vol:9 issue:5 pages:399-406
Abstract: The mechanism of the generation of potentiometric signals of corrole- and calix[4]pyrrole-containing liquid membrane electrodes was elucidated and compared in the presence of the neutral forms of phenol derivatives. In addition, the influence of lipophilic, anionic or cationic salts on this phenomenon was explored. Finally, the relationship between the acid-base properties of the phenolic guests and the hydrogen bond donor activity of the calix[4]pyrrole and corrole hosts, and the influence on the molecular recognition phenomenon occurring at the organic/aqueous interface are discussed.
URI: 
ISSN: 1386-2073
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Design and Synthesis
× corresponding author
# (joint) last author

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