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Title: Synthesis and non-linear properties of conjugated poly-unsaturated amino carbene complexes
Authors: Licandro, E ×
Maiorana, S
Papagni, A
Hellier, P
Capella, L
Persoons, Andre
Houbrechts, Stephan #
Issue Date: Jan-1999
Publisher: Elsevier science sa
Series Title: Journal of Organometallic Chemistry vol:583 issue:1-2 pages:111-119
Abstract: A series of poly-unsaturated pyrrolidino carbene complexes have been synthesized and their first beta hyperpolarizabilities evaluated using the Hyper Rayleigh Scattering (HRS) technique. Some of these complexes have good to high beta values (up to 543 x 10(-30) esu). A comparison of the non-linear responses of the complexes with those of the corresponding amides (their isolobal organic analogues) highlighted the potential usefulness of the pentacarbonylchromium carbene moiety as an electron-accepting group in the design of second order non-linear optical (NLO) materials. (C) 1999 Elsevier Science S.A. All rights reserved.
ISSN: 0022-328X
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Molecular Imaging and Photonics
× corresponding author
# (joint) last author

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