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Title: Recognition of chiral catechols using oxo-titanium phthalocyanine
Authors: Muranaka, Atsuya ×
Okuda, M
Kobayashi, N
Somers, K
Ceulemans, Arnout #
Issue Date: Jan-2004
Publisher: Amer chemical soc
Series Title: Journal of the American Chemical Society vol:126 issue:14 pages:4596-4604
Abstract: Oxo-titanium phthalocyanine (TiOPc) derivatives of catechin and hematoxylin (natural orthodiol type chiral compounds) have been prepared and characterized by spectral and chromatographic techniques. It is demonstrated that the TiOPc unit is an excellent template for chiral recognition through its isolated Q-transitions. The formation of a helical dimeric complex with hematoxylin induces strong CD-activity in the Q-band region. Ab initio geometry optimizations were combined with a Kuhn-Kirkwood coupled-oscillator mechanism to obtain the absolute configuration of hematoxylin. In addition, it is shown that the described chiroptical recognition method is sensitive to slight conformational changes.
ISSN: 0002-7863
Publication status: published
KU Leuven publication type: IT
Appears in Collections:Occupational, Environmental and Insurance Medicine (-)
Quantum Chemistry and Physical Chemistry Section
× corresponding author
# (joint) last author

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